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More technically, the divergence represents the volume density of the outward flux of a vector field from an infinitesimal volume around a given point.
A Gaussian surface is a closed surface in three-dimensional space through which the flux of a vector field is calculated; usually the gravitational field, the electric field, or magnetic field.
More precisely, the divergence theorem states that the outward flux of a vector field through a closed surface is equal to the volume integral of the divergence of the region inside the surface.