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Electrolytes studied in 100% trifluoroacetic acid exhibit a minimum in equivalent conductivity with increasing solute concentration.
Normal concentration of an ionic solution is intrinsically connected to the conductivity (electrolytic) through the equivalent conductivity.
A modest correlation has been made with the counterion condensation and the polycation conformations in order to explain the relative magnitude of limiting equivalent conductivities.
Fuoss extrapolations have been used to evaluate the limiting equivalent conductivities and association constants of the ammonium and alkali metal trifluoroacetates.
For ions with a single charge, the equivalent conductivity is equal to the molar conductivity, Lm, obtained by dividing the conductivity by its molar concentration, m.
Measurements of the equivalent conductivity of aqueous solutions of lithium, sodium, potassium, and cesium salts of carboxymethylcellulose (CMC) at 25 °C are reported.
Kohlrausch's Law Kohlrausch's Law states that the equivalent conductivity of an electrolyte at infinite dilution is equal to the sum of the ionic motilities of the ions produced by the electrolyte.
The density measurements coupled with limiting equivalent conductivities and dissociation constants, calculated by means of the Fuoss–Hsia equation, permit a more precise treatment of the conductivities of solutions at concentrations where the equivalent conductivity minimum occurs.
