reaction intermediate

His group also made important contributions in the study of reaction intermediates.

The method applies equally to cyclic reaction intermediates and transition states.

Reaction intermediates are often free radicals or unstable ions.

Many reaction intermediates with variable stability can thus be envisaged during the course of a reaction.

Reaction intermediates may be trapped in a trapping reaction.

Due to this, carbenes are highly reactive electrophiles and generated as reaction intermediates.

Reaction intermediates are very short-lived, and are actually thermodynamically unstable rather than "metastable".

Instead they act either by deactivating catalysts, or by removing reaction intermediates such as free radicals.

Several additional reaction intermediates occur interposed.

The efficiency of the reaction may also be improved by the interactions of His74 and Asn147 with reaction intermediates.

Enediols are reaction intermediates in the Lobry-de Bruyn-van Ekenstein transformation.

Returning to the NRC in 1979, he developed an innovative new program studying organic reaction intermediates using laser techniques.

A stepwise reaction is a chemical reaction with one or more reaction intermediates and involving at least two consecutive elementary reactions.

In the example above, the steps include This is, in fact, an example of a chain reaction involving reaction intermediates called radicals (see chapter 9).

Pump-probe spectroscopy can use ultrafast laser pulses to measure reaction intermediates in the femtosecond timescale.

The buildup of reaction intermediates can also increase the level of 2,3-bisphosphoglycerate (2,3 BPG) in the cells and affect tissue oxygenation.

Using the matrix isolation technique, short-lived, highly-reactive species such as radical ions and reaction intermediates may be observed and identified by spectroscopic means.

The related protein, gamma-delta resolvase shares high similarity to Hin, of which much structural work has been done, including structures bound to DNA and reaction intermediates.

This research will be used to clarify the production, structure and reactivity of critical reaction intermediates and transient species, and will focus on the dynamics of elementary chemical reactions.

By using the IRFEL, chemists will be able to probe basic molecular dissociation processes and produce unusual transient species such as organic free radical sand reaction intermediates.

These inter-domain tunnels connect the three distinct active sites, and function as conduits for the transport of unstable reaction intermediates (ammonia and carbamate) between successive active sites.

Such versatility arises from the ability of PLP to covalently bind the substrate, and then to act as an electrophilic catalyst, thereby stabilizing different types of carbanionic reaction intermediates.

Notice the unique characteristic of ACP, which is vital to fatty acid synthesis in its role of shuttling the reaction intermediates between the α and β subunits' catalytic domains.

Channeling can make a pathway more rapid and efficient than it would be if the enzymes were randomly distributed in the cytosol, and can also prevent the release of unstable reaction intermediates.

When side products or reaction intermediates are formed, the IUPAC recommends the use of the terms rate of appearance and rate of disappearance for products and reactants, properly.