hydroperoxide

These catalysts speed up the reduction of the hydroperoxide intermediates.

If the R' is hydrogen, the compound is called an organic hydroperoxide.

Once free radicals are formed, they react in a chain to convert the material to a hydroperoxide.

This hydroperoxide is reduced to the quinole with sodium thiosulfate.

It yields a volatile hydroperoxide ether that upon heating can result in a serious explosion.

Oxymercuration of alkenes followed by reaction with a hydroperoxide proceeds similarly.

Industrially, tert-butyl hydroperoxide is used as a starter of radical polymerization.

In this process ethylbenzene is treated with oxygen to form the ethylbenzene hydroperoxide.

This is attributed to enzymatic activity of hydroperoxide lysases when exposed to a high oxygen environment not present in the cells.

These include hydrazine, hydroxylamine, the hypochlorite ion and the hydroperoxide anion.

The hydroperoxide anion is a more reactive nucleophile than neutral hydrogen peroxide.

This hydroperoxide is then used to oxidize propylene to propylene oxide.

The reaction requires t-butyl hydroperoxide and generally a metal and proceeds through a radical mechanism.

In the presence of oxygen, dibutyl ether is oxidized to a peroxide or hydroperoxide.

Organosulfur compounds are efficient hydroperoxide decomposers, which thermally stabilize the polymers.

At the second step, the nucleophilic hydroperoxide or halogen anion attacks the boron atom.

The addition of oxygen results in a more active radical which can further extract hydrogen atoms and release the hydroperoxide, leaving a new radical.

The oxidizing agent is tert-butyl hydroperoxide.

All of the reactants associate with the polyleucine catalyst prior to reaction to form the hydroperoxide enolate intermediate.

The cumene hydroperoxide (CHP) is concentrated in this section.

The formation of the hydroperoxide intermediate (2) is catalyzed by the loss of the indole proton.

The oxidation of a Grignard reagent with oxygen takes place through a radical intermediate to a magnesium hydroperoxide.

Products of decomposition of cumene hydroperoxide are methylstyrene, acetophenone and cumyl alcohol.

An important oxidation product is verbenone, along with pinene oxide, verbenol and verbenyl hydroperoxide.

Peroxiredoxins are frequently referred to as alkyl hydroperoxide reductase (AhpC) in bacteria.