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Some compounds break down endothermically when subjected to high temperatures.
They endothermically decompose releasing both water and carbon dioxide, giving fire retardant properties to the materials in which they are incorporated.
Hydromagnesite decomposes endothermically, giving off water and carbon dioxide, leaving a magnesium oxide residue.
What you need to recognize is that the factors governing the solubility of many, if not most salts, are NOT whether the solution forms exothermically or endothermically.
Energy requirements are lower because of the lower kiln temperatures required for reaction, and the lower amount of limestone (which must be endothermically decarbonated) in the mix.
For such purpose, inert materials (e.g. clay, diatomaceous earth, alumina, silica, magnesium oxide, or others) or endothermically decomposing materials (e.g. carbonates) are added.
Although calcium reacts exothermically with EDTA (heat of chelation -23.4 kJ/mol), magnesium reacts endothermically with a heat of chelation of +20.1 kJ/mol.