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The anhydrous form is produced from hydrogen fluoride and chromic chloride:
Chromium(III) chloride, also known as chromic chloride or chromium trichloride.
Chromium pentafluoride is one of the products of the action of fluorine on a mixture of potassium and chromic chlorides.
• Chromium (III)/Chromic chloride hexahydrate (O'Neil et al.
In their original 1977 publication, Tamejiro Hiyama and Hitosi Nozaki reported on a chromium(II) salt solution prepared by reduction of chromic chloride by lithium aluminium hydride to which was added benzaldehyde and allyl chloride: