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Carbon dioxide clathrate is believed to play a major role in different processes on Mars.
Deep sea deposition of carbon dioxide clathrate has been proposed as a method to remove this greenhouse gas from the atmosphere and control climate change.
Typical guests forming Type I hydrates are CO in carbon dioxide clathrate and CH in methane clathrate.
Fleyfel, F. and Devlin, J. P. (1991) Carbon Dioxide Clathrate Hydrate Epitaxial Growth: Spectroscopic Evidence for Formation of the Simple Type-II CO Hydrate.