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The arene ring has an ability to stabilize charges.
In these reactions it is the arene that is excited.
This metabolite, arene oxide, is normally very toxic to cells.
Electron transfer to a second molecule of arene carries on the radical chain.
Double bonds and arene fragments tend to resist fragmentation.
It exists in three forms, depending on arene substitution patterns:
The arene can be liberated from the chromium with iodine or by photolysis in air.
An aromatic hydrocarbon, or arene, is a hydrocarbon ring compound.
It was probably identical with the Homeric Arene.
Subsequent to nucleophilic addition, the modified arene can be recovered from the metal.
Organoleads find use in coupling reactions between arene compounds.
Triptycenes, with the alkene groups part of an arene, are related compounds.
The reaction product is an alkylated arene compound.
Many derivatives also isomerize to the corresponding arene compounds.
In general, these conditions were not able to couple primary amines due to competitive hydrodehalogenation of the arene.
Arene may also refer to:
Species within the genus Arene include:
The arene must be electron-rich i.e. phenol or aniline type.
This step is followed by nucleophilic attack of the arene toward the acyl group:
For sure, the presence of more than one hydroxyl group on a benzene ring or other arene systems does not make them "polyphenols".
In contrast to regular nucleophilic aromatic substitution, deactivating groups on the arene are not required.
This second approach may be more appropriate for arene ligands containing thermally fragile substituents.
This molecule has a unique symmetric arene substitution pattern of a trisubstituted benzene.
For instance the following example shows the nucleophilic abstraction of H from an arene ligand attached to chromium.