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It is a secondary, low-temperature mineral, associated with annabergite, fluorite, baryte and sphalerite.
Nickeline, a principal ore of nickel that is also known as niccolite, weathers at the surface into a green mineral (annabergite) that resembles malachite.
Kambaldaite is associated with goethite, malachite, annabergite, gaspeite and magnesite in the nickel sulfide gossans of Kambalda and Widgiemooltha.
It was long known (since 1758) under the name nickel ochre; the name annabergite was proposed by H. J. Brooke and W H. Miller in 1852, from Annaberg in Saxony, one of the localities of the mineral.