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An azirine is an intermediate in the Neber rearrangement.
In the Neber rearrangement certain oximes are converted to the corresponding alpha-amino ketones.
The Neber rearrangement offers an alternative to electrophilic amination through the intermediacy of an azirine.
The Neber rearrangement is an organic reaction in which an oxime is converted into an alpha-aminoketone in a rearrangement reaction.