multidentate ligand

The use of multidentate ligands can also control the arrangement of substituents.

Chelate: a multidentate ligand, containing more than one donor atom.

Multidentate ligands stabilize metal complexes and provide a means of fine-tuning metal-centered reactivity.

A particularly important group of multidentate ligands is that where the donor atoms form part of or are attached to a large, cyclic molecule.

The data are compared with previously reported work by other authors for substitution at nickel(II) with related monodentate and multidentate ligands.

Synthesis, structure and kinetics of group 6 metal carbonyl complexes containing a new 'P2N' mixed donor multidentate ligand.

For these cases, multidentate ligands were usually employed to chelate with the metal, which activates both the zwitterionic enolate and the aldehyde.

Garth has looked at a series of complexes and finds an intermediate only in those complexes that photoaquate one end of multidentate ligand.

Key words: multidentate ligand, tetraazamacrocyclic compound, dioxopolyaza macrocycles, cyclic amides, copper(II) complexes.

The new potentially multidentate ligand (EDDA-KA)2 has been prepared and its acid-base properties determined.

In other words, a chelating agent is a multidentate ligand used in some liquid formulations as a stabilizer to complex metals which might promote instability (eg.

The synthesis of Group 15 ligands (PR3, AsR3 etc) will precede a discussion of multidentate ligand design and synthesis.

Coordination Chemistry Associate Professor Vagg The synthesis and properties of transition metal complexes of multidentate ligands containing amide groups and of macrocyclic tetradentates.

No compounds with steric numbers this high involving monodentate ligands exist, and those involving multidentate ligands can often be analysed more simply as complexes with lower steric numbers when some multidentate ligands are treated as a unit.