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The reasons behind this can be explained by ligand field theory.
This type of complex is common when metals are in different ligand fields.
His interests lie in the area of ligand field theory and its application to rare earth systems.
The ligand field parameters have been evaluated and are in keeping with the proposed structures.
Application to problems in ligand field theory of transition metal ions.
The more recent ligand field theory offers an easy to understand explanation that models phenomenon relatively well.
Relatively detailed descriptions are provided by ligand field theory.
Preliminary ligand field calculations point against the likelihood of the splitting being electronic in nature.
The pre-edge contains information about ligand fields and oxidation state.
Strong ligand fields lead to low-spin complexes which cause some exceptions to 18-electron rule.
The charge of the metal center plays a role in the ligand field and the Δ splitting.
They are qualitatively useful and can be used to approximate the value of 10Dq, the ligand field splitting energy.
Broadening of the I 4d spectrum is due to vibrational and ligand field splittings.
Free-ion Terms and the effects of ligand fields in weak and strong field approximations.
Ligand field theory a development of crystal field theory taking covalency into account.
The ligand field strength of 4-methylpyridine is found to be indistinguishable from that of pyridine in these complexes.
Ligand field theory as a special case of Molecular Orbital Theory.
The inclusion of a ligand field contribution allows computations on "open-shell" metalloproteins.
Griffith and Orgel championed ligand field theory as a more accurate description of such complexes.
Upon the development of Ligand Field Theory, it became evident that equilibrium could exist between spin states.
In each case, the photosensitivity was greater for charge transfer excitation than ligand field excitation.
Ligand field Co(III) excited states are clearly indicated to be effective.
Quantitative basis of ligand fields.
Conversely, a HS state occurs with weaker ligand fields and smaller orbital splitting.
This is used in the Hückel method, ligand field theory, and the Woodward-Hoffmann rules.