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The transition from semiconduction to ionic conduction occurred gradually as the sodium oxide concentration increased.
This junction of the two crystals (or parts of one crystal) created a solid-state diode, and the concept soon became known as semiconduction.
The liquid ferric vanadates exhibited n-type semiconduction properties at oxygen partial pressures greater than 0.1 atm.
The liquid sodium vanadates exhibited n-type semiconduction properties at sodium oxide concentrations less than 10 mol% and ionic conduction properties at concentrations greater than 25 mol%.
Lars Onsager 1962 "In recognition of his critical study and precise expression of the principles of conduction in electrolytes and fused salts; for useful equations defining these principles, for fundamental concepts of superconduction and semiconduction; for his stimulating leadership in physical science"