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At pH higher than 13.5, however, oxidation does not occur, possibly due to deprotonation of the second peroxidic oxygen.
For safety reasons, peroxidic compounds are stored in a cool, opaque container, as heating and illumination accelerate their chemical reactions.
Deprotonation of the second peroxidic oxygen would prevent [1,2]-aryl migration because the lone oxide anion is too basic to be eliminated (2).
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